Separation of uranium by anion exchange pdf free download. When the valuable metal is a rare earth, the resin should be substantially free of phosphate. Ion exchange resins advances in research and application. Pdf present and future applications of ion exchange in. The weakbase anion exchange resin with a primary amine functional group was the best performing resin among the anion exchange resins. The rock is dissolved in acid and added to an anion exchange column that is pretreated with 9. The dowex resins had the highest uranium sorption, followed by lewatit, purolite and the activated carbon. Us2739934a us423401a us42340154a us2739934a us 2739934 a us2739934 a us 2739934a us 423401 a us423401 a us 423401a us 42340154 a us42340154 a us 42340154a us 2739934 a us2739934 a us 2739934a authority us united states prior art keywords uranium compartment leach liquor sulfuric acid anode prior art date 19540415 legal status the legal status is an assumption. Insights on uranium uptake mechanisms by ion exchange resins with chelating functionalities. The adsorption parameters including contact time, ph, initial uranium concentration and temperature have actually. Engineering aspects of ion exchange in hydrometallurgy.
Removalofuraniumvifromaqueoussolutionsusingglycidyl. Ion exchange technology is used for the primary recovery of metals of interest or the removal of specific impurities in order to increase the value and purity of the final product. Use add reply to replyparticipate in a topicdiscussion most frequent. The strong base anion resins have been used in south africa at vaal river operations for the last two decades. Pdf download hydrometallurgy in extraction processes. The use ion exchange resins throughout the lifecycle of a. Ion exchange is used in water treatment, including water softening, industrial demineralization, condensate polishing, ultrapure water. Ion exchange resin technology in recovery of precious and. Uranium remediation by ion exchange and sorption methods. The industry pioneered hydrometallurgical applications of ion exchange. The stream needed to be boiled for 6 h to lower the total carbonate concentration before it could be treated. The sorption of lead on anion exchange resin from nitric acidisopropyl alcoholwater mixtures.
Recovery of scandium from chloride media using the novel ion. Part i discusses the fundamentals of ion exchange, the structure, propertries and the main processes using ion exchange resins. Control of scale and corrosion is most commonly achieved by calcium removal, which is. Strongbase anion exchange resins, with quaternary ammonium functional. Ion exchange, in situ uranium recovery, restauration, acid and carbonate leaching.
Process for the recovery of uranium from a pregnant lixiviant employed in uranium leaching operations in which the uranium is concentrated by ion exchange resin. Hydrometallurgy aims to compile studies on novel processes, process design, chemistry, modelling, control, economics and interfaces between unit operations, and to provide a forum for discussions on case histories and operational difficulties. Ion exchange instead of using solvent extraction for removal of gallium, several ion exchange resins that contained iminodiacetic acid dicarboxylic acid amine c 4 h 7 no 4 as the active component were tested to recover gallium11,12. This product is certified by the wqa to nsfansi61 standard. Effect of salt form sulfate, chloride, nitrate, hydroxide, nature of sulfate, nitrate, and chloride containing compounds acids, their sodium and zinc salts, sodium carbonate and ammonium hydrocarbonate and their. After adsorption, the uranium loaded resin was separated from the solution, washed to. Compared to ion exchange resins, chelating resins have stronger bonding forces to link with metal ions with high selectivity.
Aside from its use to purify drinking water, the technique is widely applied for purification and separation of a variety of industrially and medicinally. T his chapter outlines the basic steps involved in mining, processing, and reclamation that might be suitable for uranium ore deposits in the commonwealth of virginia. The first application of ion exchange to extractive hydrometallurgy is the use of a strong base anion exchange resin for selective recovery of uranium from sulfate leach liquors. At ph 1, the adsorption selectivity of scandium can be obtained among the others metals. With the development and evaluation of new resins for uranium recovery the resistance to silica fouling is an important factor in the choice of an optimum resin6. Using add reply allows you to attach images or pdf files and provide a more complete input. Ion exchange chromatography was applied for uranium sorption, using commercially available, strongly basic anion exchanger, dowex 1.
Separation of thorium and uranium in nitric acid solution. Anion exchange resin separation of the rare earths. Applying hydrometallurgical techniques such as heap leaching figures 9 to phosphate processing could solve the problems faced in sulfuric acid route, i. Jfalsrslkyafgmuhfffaoysan uranium0 chemical compound.
Hydrometallurgy for the courses and seminars conducted as part of the phd student. It is an insoluble matrix or support structure normally in the form of small 0. Such deposits are not removed by common treatment and require special care. Ion exchange usually describes a processes of purification of aqueous solutions using solid polymeric ion exchange resin. Uranium and molybdenum recovery from copper leaching. Ion exchange is widely used in the food and beverage industry, hydrometallurgy, metals finishing, chemical, petrochemical, pharmaceutical technology, sugar and sweetener production, ground and potablewater treatment, nuclear, softening, industrial water treatment, semiconductor, power, and many other industries. The eluant also contains a base such as ammonium hydroxide in an amount sufficient to increase the ph to a value within the range of 9. Us8936770b2 hydrometallurgical process and method for. Removal of uranium from mine water using ion exchange at. Evaluation and application of anion exchange resins to. The article describes studies on the separation of uranium from acid pregnant leach solutions obtained from polish uranium ores. For uranium ore deposits, the choice of mining methods and processing options is very depositspecific and dependent on many variables such as the quality and quantity of the ore, the shape and depth of the ore deposit, site. Abstractthis study focused on separation and recovery of scandium from chloride solution using the new synthesized ion exchange resin. The effectiveness of ion exchange resins in separating.
Hydrometallurgy is a method for obtaining metals from their ores. This site is like a library, use search box in the widget to get ebook that you want. Ion exchange resins used in drinking water treatment james mcmahon dr. Ion exchange is used in nearly every part of the nuclear fuel cycle from the purification of uranium from its ore to the final recovery of uranium and transmutation products. Present and future applications of ion exchange in hydrometallurgy. Hydrometallurgy fundamentals and applications, michael l. Ion exchange resin 4,5 is the most commonly used adsorbent for this method and most of the worlds uranium hydrometallurgical plants use anion exchange resin to extract uranium. Common examples are vanadate, molybdate, chloride, and nitrate. Ion exchange also plays a valuable role in the management of nuclear wastes generated in the fuel cycle. It is known in the uranium recovery industry that anion exchange resins may be used to gather and concentrate uranium values from aqueous solutions.
A list of metals that have been recovered and purified commercially by ion exchange is given in table 1. Recently, the use of ion exchange resins and resininpulp processes have. Ion exchange resins download ebook pdf, epub, tuebl, mobi. Donia and others published removalofuraniumvifromaqueoussolutionsusingglycidylmethacrylatechelatingresins 2009 hydrometallurgy find, read and. Applications of ion exchange in hydrometallurgy springerlink. In situ leach isl mining of uranium june 2009 z most uranium mining in the usa and kazakhstan is now by in situ leach methods, also known as in situ recovery isr. Table 1 applications of ion exchange in hydrometallurgy. When an industrial facility requires ion exchange technology as part of its process, its important to not only know how much the ion exchange resins cost but also to factor in expenses associated with maintaining and disposing of them. Therefore, functional groups are bonded to the polymer beads. Jul 6, 2017 this board is all about ion exchange resin that is being used for water softeners see more ideas about ion exchange resin, ion exchange and resin. Ion exchange resins an overview sciencedirect topics.
Notes of practical application of ion exchange resins in. Metal chemical processing techniques that complement hydrometallurgy are pyrometallurgy. Ion exchange investigation for recovery of uranium from. Impact of silica on hydrometallurgical t and mechanical. Lmp anion exchange resin in the uranium adsorption. The polymer structure is gel polystyrene crosslinked with divinylbenzene with a type ii quaternary ammonium functional group. Ion exchange method, is one of the most classic uranium hydrometallurgy processes for the extraction and enrichment of uranium from solution. To separate thorium and uranium in nitric acid solution using anion exchange process, a strong base silicabased anion exchange resin sipyrn4 was synthesized. The extraction and recovery of metals from their ores by processes in which aqueous solutions play a predominant role.
A wide variety of process streams benefit from the application of ion exchange resins, as shown in table 1. New ion exchange resin for uranium recovery industrial. S6328 a resins and silver impregnated activated carbon to examine uranium sorption and extraction for each material. The beads are typically porous, providing a large surface area on and inside them. The effectiveness of ion exchange resins in separating uranium and thorium from rare earth elements in acidic aqueous sulfate media. Chemical exchange isotope separation requires segregation of two forms of an element into separate but contacting streams. The results of joint uranium and rhenium sorptions from the solutions with strong base anion exchange resin ambersep a920u herein after a920, are presented in the paper. Sorption and binary exchange of nitrate, sulfate, and. Acs members enjoy benefits including 50 free articles a year and reduced priced individual subscription. More precisely, the term encompasses a large variety of processes where ions are exchanged between two electrolytes. Application of an ion exchange loading correlation for nickel. These functionalized polymers adsorb particular anions or cations from the liquid and discharge others.
Batch experiments were conducted and the separation factor of thorium and uranium in 9 m nitric acid was about 10. Part 2 covers the recovery of uranium from acidic or alkaline leach liquors. Ion exchange resin anion exchange resin, cation exchange. Ion exchange resins remove harmful contaminants from liquids, replacing them with beneficial, desired ions. As one of the leading hydrometallurgy ion exchange resin manufacturers and suppliers in china, we warmly welcome you to wholesale discount hydrometallurgy ion exchange resin made in china here from our factory. Hydrometallurgy article about hydrometallurgy by the free. Ion exchange offers various grades of chelating resins, strong and weak acid cation exchange resins for removing or recovering metal ions. Contact was made over a period of 24 hours under ambient conditions. Water treatment is the bestknown and biggest field of application for ion exchange resins. In 1953, the union of soviet socialist republics ussr introduced the resinin pulp. The symposium is being organized by the hydrometallurgy section of the metallurgical society of cim and will constitute the 36th annual hydrometallurgical meeting.
Recoveries from all ion exchange resins were in the range of 94e99% for aqueous uranium in the environmentally relevant. Uranium pcil 2781 30 well depth 575625 ft 700950 ft. Chem eng 7058 hydrometallurgy and electrometallurgy. How much does it cost to buy, maintain, and dispose of ion. The use of ionexchange membranes in the hydrometallurgy of. Ion exchange resins are used to remove dissolved particles from liquids. Hydrometallurgy is the process of extracting metals from ores by dissolving the ore containing the metal. The first hydrometallurgical application of ion exchange resins was for uranium recovery. It is a technique within the field of extractive metallurgy involving the use of aqueous chemistry for the recovery of metals from ores, concentrates, and recycled or residual materials. The ion exchange resin is eluted with an eluant containing 0.
Sorption of rhenium and uranium by strong base anion exchange resin from solutions with different anion compositions. Hydrometallurgy ion exchange offers various grades of chelating resins, strong and weak acid cation exchange resins for removing or recovering metal ions. Us4280985a process for the elution of ion exchange. The major species in solution is the uranyl trisulfate tetra anion. Pdf ion exchange has traditionally been employed for water. The resin containing glycol amic acid groups shows the possibility to recover scandium from chloride aqueous solutions. Anion exchange in dilute sulphuric acid has been used for some time to recover uranium vi from lowgrade ores by hydrometallurgy. The ion exchange process used to extract uranium from the leaching solution is based on the high binding constants of the anionic sulfate complexes of uranium relative to the anion on the anion exchange resin chloride, primarily due to their higher negative charge.
Other industrial applications include gold recovery and purification of electrolytes for electrowinning. Anion exchange and a selectivity scale for elements in. Separation of thorium by anion exchange analytical chemistry. The results of uranium u and rhenium re sorption from solutions containing both metals by an21 weakly basic anion exchange resin are presented in this paper. In the current experiment, feasible separation of uvi and thiv from reiii was attained at 0. The chelating resins having aminophosphonic, iminodiacetate, thiol and thiouronium functional groups are used for removing specific ions from a mixture of ions. Uranium vi adsorption equilibrium on purolite resin sga. Pdf regularities of rhenium and uranium sorption from mixed. The resins studied comprised strong and weakbase anion exchange resins, and strong and weakacid cation exchange resins. The adsorption of europlum and cerium on a strong base anion exchange resin from dilute nitric acid solutions containing aliphatic alcohols.
The influence of the major variables on column operation is described, plant performance data are summarized, cost factors are enumerated, and the probable application of this operation to metals at least as valuable. The mixed bed ion exchange resin lewait ionac nm 60 regeneration lewatit ionac nm 91 nonregeneration is a mixed bed ion exchange containing a mixture of gelic, strong cation exchange resin acid and gelic, strong anion exchange resin alkaline type i in fully regenerated form in the ratio 55. Chapters cover ion exchange in uranium extraction, the extraction of precious metals in activated carbon, extraction of platinum group metal ions by ion exchange resins. Ion exchange ix is the reversible interchange of ions between a solid and a liquid such as water. The selectivity of these resins to adsorb uvi and thiv in the presence of. Hydrometallurgy is concerned with the selective leaching of metallic compounds to form a solution from which the metals hydrometallurgy originated in the 16th century, but its principal development took place in the 20th century, stimulated partly by the desire to extract gold from lowgrade ores. Pdf hydrometallurgical process for uranium production. The production rates are limited by the amount of uranium loading per unit of resin and the rate of flow of crude liquors as a function of density. Hydrometallurgical process and method for recovering metals download pdf. More recently first uranium has installed a resin plant for the recovery of uranium.
Ion exchange, hydrometallurgy, uranium, precious metals, base metals. Ion exchange the bestknown metallurgical application of ion exchange is in the recovery of uranium a south africandeveloped process in which mintek, with its nimcix fluidisedbed contactor, played a major role. Hydrometallurgy of phosphate rock and the recovery of uranium 123. Strongbase anionexchange resins, with quaternary ammonium. Ion exchange investigation for recovery of uranium from acidic pregnant leach solutions. A detailed discussion about the recent advances of the ion exchange technique in metal recovery from their pregnant solutions is also presented from the aspects of anion metal adsorption on the resins and metalloaded resin elution. All our customized water filtration medias are with high quality and competitive price. It can be used to separate and recycle metal ions into various fields such as amine acid separation, hydrometallurgy and the prevention of pollutants into the waste stream. Two distinct processes are involved in hydrometallurgy. Ion exchange resins show good selectivity with respect to metal ions. Results indicate that although so42 carries divalent negative charges, it showed the least selectivity for sorption by the purolite a520e resin, which is. Contact us for free sample, pricelist and quotation.
Competitive ion exchange reactions were studied on a strongbase anion exchange resin to remove no3 and uranium from a contaminated groundwater containing high levels of no3. Click download or read online button to get hydrometallurgy in extraction processes book now. Uranium adsorption on ionexchange resins batch testing. The uranium adsorption performance of five resins dowex 1, dowex 21k 1630 fresh, dowex 21k 1630 regenerated, purofine pfa6004740, and resintech sir1200 were tested using unspiked, nitratespiked, and nitratespikedph adjusted source water from well 299w1936. This paper gives a comprehensive overview of the chemical and physical requirements that need to be accommodated by ix resins in the various applications. China hydrometallurgy ion exchange resin suppliers.
The uses and advantages of ion exchange resins for sorption and recovery of. The rock is dissolved in acid and added to an anionexchange column that is pretreated with 9 moll. Ion exchange resins for water treatment by adsorption. These costs can be difficult to narrow down because of the many types of resins available on the market today there are thousands in addition to all the. Anion exchange behaviour of uranium, thorium and lanthanides in organic solvent mixtures. Kinetic study of ultrasonicassisted uranium adsorption by. Electrodialysis with ion exchange membranes is important in chemistry, chemical technology and hydrometallurgy as a basic operation which eliminates the usual chemical neutralization and makes it possible to remove excess acidity and alkalinity, to separate mixtures of elements whose properties are similar and to extract radioactive products from waste waters. Conventional ion exchange resins with different functional groups were evaluated for their potential application in separating uranium uvi and thorium thiv from rare earth elements reiii. In namibia, rossing uranium and langer heinrich are using resin for recovery of uranium and there is a new mine under development by uramin at trekkopje. Ion exchange resins for uranium recovery free patents online. Download free hydrometallurgy in extraction processes book in pdf and epub free download. An ion exchange resin or ion exchange polymer is a resin or polymer that acts as a medium for ion exchange. Uranium carbonate industrial waste streams from a brazilian nuclear production plant were treated by an ion exchange process using a type ii strong base anion exchange resin, ira910a with a dimethyl 2hydroxy ethyl functional group. In some cases, the scale of operation is relatively small, e.
Removing radioactive contamination from ion exchange resins. Each extractive situation must be assessed on its own merits by the. Due to the near neutral ph at the rifle site and the expected dominance of anionic. Anion exchange is great tool to exchange or eliminate contaminants in low concentrations and can help in identifying the ion exchange unit that is most effective for treatment.
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